Bond-Stretch Isomerism: Trapped Isomeric Structures of Hexacoordinate Copper(II) Bispidine Chromophores along a Jahn-Teller Active Vibrational Coordinate
P. Comba, A. Hauser, M. Kerscher and H. Pritzkow
Angewandte Chemie International Edition
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42
(37) (2003), p4536-4540
DOI:
10.1002/anie.200351900
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unige:3511
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Abstract
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Copper(II) complexes of the pentadentate bispidine ligands exist in two isomeric forms (see structure) with bond-length differences up to 0.5 Ã…. The stabilization of either isomer may be achieved by a variation of the substituent at N7.
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